MATERIAL SAFETY DATA SHEET
Finished Product
Date-Issued: 8/5/2004
MSDS Ref. No: RX201-16
Date-Revised: 8/5/2004
Revision No: New MSDS
ECG Electronics Degreaser & Wash
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
ECG Electronics Degreaser & Wash
PRODUCT DESCRIPTION:
Electronic Component Degreaser
PRODUCT CODE:
RX201-16
MARKETER
NTE Electronics, Inc.
44 Farrand Street
Bloomfield, NJ 07003
Phone: 973-748-5089
24 HR. EMERGENCY TELEPHONE NUMBERS
CHEMTREC (U.S.):
(800) 424-9300
CANUTEC:
(613) 996-6666
Emergency Phone:
1-800-631-1250 8:00 am – 5:00 pm EST
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
1,2-transdichloroethylene (Trans)
1,1,1,3,3-Pentaflouropropane (HFC-24fa)
Ethanol
1,1,1,2-Tetraflouroethane (HFC-134a)
Carbon Dioxide
EEC LABEL SYMBOL AND CLASSIFICATION
R20
–
Harmful by inhalation.
EEC Harmful – “Xn”
R36/37/38– Irritating to eyes, respiratory system and skin.
EEC Irritant – “Xi”
R52/53– Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
EEC Environment – “N”
Wt. %
40-80
10-50
1-20
10-20
1-10
CAS#
156-60-5
460-73-1
64-17-5
811-97-2
124-38-9
EINECS#
205-860-2
4191706
200-578-6
223770
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
PHYSICAL APPARANCE:
Transparent, colorless liquid.
IMMEDIATE CONCERNS:
Warning! High concentrations of vapor can reduce oxygen available for breathing.
Harmful if inhaled. May decompose on contact with flames or extremely hot metal surfaces to produce toxic and
corrosive products.
POTENTIAL HEALTH EFFECTS:
EYES:
Substance causes substantial eye irritation.
SKIN:
Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin
irritation and dermatitis (rash).
INGESTION:
Substance may be harmful is swallowed.
INHALATION:
High concentrations in immediate area can displace oxygen and can cause dizziness,
unconsciousness, and possibly death with longer exposure. Keep people away from such vapors without self-
contained breathing apparatus.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
EYES:
Liquid splashed in the eye may cause redness, irritation and conjunctivitis.
SKIN:
Prolonged exposure causes redness, pain, drying, and cracking of the skin.
INGESTION:
For large amounts, abdominal pain, nausea and vomiting.
INHALATION:
High concentrations may lead to central nervous system effects (drowsiness, nausea, headaches,
paralysis and loss of consciousness.)
ACUTE TOXICITY:
Overexposure may cause dizziness and loss of concentration. At higher levels, CNS
depression and cardiac arrhythmia may result.
4. FIRST AID MEASURES
EYES:
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue
flushing for at least 15 minutes. Have eyes examined and tested by medical personnel.
SKIN:
Immediately flush skin with plenty of water. Remove clothing. Get medical attention immediately. Wash
clothing separately before reuse.
INGESTION:
If swallowed, gently wipe or rinse the inside of the mouth with water. DO NOT induce vomiting.
Sips of water may be given if person is fully conscious. Never give anything by mouth to an unconscious or
convulsing person. Immediately contact a poison control center, emergency room or physician as further
treatment may be necessary.
INHALATION:
Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained
personnel. Seek immediate medical attention.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD:
None:….ASTM D-56 (Tag C.C.)
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this
material.
FIRE FIGHTING PROCEDURES:
Use water spray to keep fire-exposed containers cool and to knock down
vapors, which may result from product decomposition.
FIRE FIGHTING EQUIPEMENT:
As in any fire, wear self-contained breathing apparatus pressure-demand,
(MSHA/NIOSH approved or equivalent) and full protective gear.
HAZARDOUS DECOMPOSITION PRODUCTS:
Toxic oxides of carbon and corrosive vapors of hydrogen
chloride.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL:
Contain spill with dike to prevent entry into sewers.
LARGE SPILL:
If this material is released into a work area, evacuate the area immediately.
GENERAL PROCEDURES:
Dike area to contain spill. Take precautions as necessary to prevent contamination of
ground and surface waters. Recover spilled material on adsorbent, such as sawdust or vermiculite, and sweep into
closed containers for disposal. After all visible traces, including vapors, have been removed thoroughly wet vacuum
the area. Do not flush to sewer. If area of spill is porous, remove as much contaminated earth, gravel, etc. as necessary
and place in closed containers for disposal.
SPECIAL PROTECTIVE EQUIPMENT:
Only personnel equipped with proper respiratory and skin/eye protection
should be permitted in area. See Section 8 for details.
7. HANDLING AND STORAGE
HANDLING
Use with sufficient ventilation to keep employee exposure below recommended limits. Provide
adequate ventilation for storage, handling and use, especially for enclosed or low spaces. Avoid contact of liquid with
eyes and prolonged skin exposure. Do not allow product to contact open flame or electrical heating elements because
dangerous decomposition products may form.
STORAGE:
Store away from heat.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL
Ppm mg/m³
TWA
NE[1]
STEL
NE
ACGIH TLV
ppm mg/m³
200
200
Supplier OEL
ppm mg/m³
NE
1,2-Transdichloroethylene (Trans)
1,1,1,3,3-Pentaflouropropane (HFC – 24fa)
Ethanol
1,1,1,2 – Tetraflouroethane (HFC – 134a)
TWA
NONE
STEL
NONE
TWA
1000
STEL
NL
TWA
NE
1900
NL
NONE
NONE
1000
NL
NE
1880
NL
NL
NL
300
NL
NL
NL
1,000 [2]
OSHA TABLE COMMENTS:
1.
NOT ESTABLISHED
2.
* (AEL)=Acceptable Exposure Limit as established by the manufacture
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE:
For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
contact, wear splash-proof goggles.
SKIN:
The glove(s) listed below may provide protection against permeation. Gloves of other chemically resistant
materials may not provide adequate protection.
Viton, Solvex, Butyl, Buna, Neoprene.
RESPIRATORY:
A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator’s use.
OTHER USE PRECAUTIONS:
Emergency shower and eyewash facility should be in close proximity.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR:
Faint ethereal odor
APPEARANCE:
Clear, Colorless liquid
PERCENT VOLATILE:
100
VAPOR PRESSURE:
17.8 psi at 20˚ C (68˚ F)
EVAPORATION RATE:
>1 (TCE=1)
SPECIFIC GRAVITY:
1.229 (water=1)
(VOC):
858.6 g/L (non exempt VOC)
10. STABILITY AND REACTIVITY
STABLE:
YES
HAZARDOUS POLYMERIZATION:
NO
CONDITIONS TO AVOID:
Stable. However, may decompose if heated.
STABILITY:
Stable.
POLYMERIZATION:
Will not occur.
HAZARDOUS DECPMPOSITION PRODUCTS:
May form hydrochloric and hydrofluoric acids – possibly
carbonyl halides, when exposed to high temperatures.
INCOMPATIBLE MATERIALS:
Oxidizing agents, alkalies and bases.
11. TOXICOLOGICAL INFORMATION
ACUTE
EYES:
Moderately to severely irritating.
DERMAL LD50:
Mildly to moderately irritating.
ORAL LD50:
Slight to very low toxicity.
INHALATION LC50:
Slight to very low toxicity.
TERATOGENIC EFFECTS:
Test results indicate this compound/mixture is not teratogenic.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA:
There is limited information available on the environmental fate and effects of this
material. The primary environmental concern for release is the impact on aquatic and terrestrial species. Due care
should be taken to avoid the accidental release of this material into the environment.
ECTOXICOLOGICAL INFORMATION:
Invertebrate toxicity: LC50 (30 min) Photobacterium phosphoreum =
1540 ppm Microtoxicity test.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD:
Recover by distillation or remove to permitted waste disposal facility. Comply with Federal,
State and Local regulations.
FOR LARGE SPILLS:
Contaminated sawdust, vermiculite, or porous surfaces must be disposed of in a permitted
hazardous waste management facility. Recovered liquids may be reprocessed or incinerated or must be treated in a
permitted hazardous waste management facility.
GENERAL COMMENTS:
Dispose of in a manner consistent with federal, state, and local regulations.
14. TRANSPORATION INFORMATION
DOT (DEPARTMENT OF TRANSPORATON)
PROPER SHIPPING NAME:
CONSUMER COMMODITY ORM-D
PRIMARY HAZARD CLASS/DIVISION:
No classification
UN/NA NUMBER:
N/A
PACKING CODE GROUP:
N/A
AIR (ICAO/IATA)
PROPER SHIPPING NAME:
CONSUMER COMMODITY ID8000
PRIMARY HAZARD CLASS/DIVISION:
9
UN/NA NUMBER:
ID8000
PACKING CODE GROUP:
N/A
IATA NOTE:
Domestic shipments only. When shipping International contact TechSpray shipping department.
VESSEL (IMO/IMDG)
PROPER SHIPPING NAME:
AEROSOLS IN LIMITED QUANTITES OF CLASS 2
PRIMARY HAZARD CLASS/DIVISION:
2.2
UN/NA NUMBER:
UN1950