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CCK-18LED

LED Lighting Development Tools Deluxe Chemical Compatibility Kit

器件类别:开发板/开发套件/开发工具   

厂商名称:Cree(科瑞)

厂商官网:http://www.cree.com/

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器件参数
参数名称
属性值
Product Attribute
Attribute Value
制造商
Manufacturer
Cree(科瑞)
产品种类
Product Category
LED Lighting Development Tools
RoHS
Details
产品
Product
Test Kits
用于
For Use With
18 LEDs
Description/Function
Chemical compatability kit
工厂包装数量
Factory Pack Quantity
10
文档预览
CLD-AP63 rev 6 JAnuAry, 2018
Support Document
Cree
®
XLamp
®
LEDs
Chemical Compatibility
figure 1: XLamp
®
LED discolored as a result of exposure to incompatible chemicals
TabLE of ConTEnTs
executive Summary ......................................................................1
Background and Introduction .......................................................2
examples of Chemical Incompatibility ........................................3
reversibility of vOC-Based Discoloration....................................6
Material Selection Considerations ...............................................8
Chemical Compatibility Testing ...................................................9
Chemical Compatibility Test Procedure ................................11
evaluation ................................................................................12
Provide Post-Test Information to Cree ..................................12
Chemical Compatibility Test Kit Availability ..........................13
Conclusion...................................................................................13
Helpful Links................................................................................13
Appendix ......................................................................................14
EXECuTivE summary
The presence of incompatible volatile organic compounds
(vOCs) in LeD-based solid-state lighting (SSL) designs can impair
the performance and reduce the lifetime of these illumination
systems. Glues, conformal coatings, O-rings, gaskets, and
potting compounds are examples of materials frequently used
in the construction of LeD-based luminaires or lamps and often
contain vOCs. The presence of chemically incompatible vOCs
on or near LeDs can degrade the light output levels or cause
changes in the chromaticity point of the light. The photograph
in Figure 1 above is an example of this vOC degradation on
the surface of an LeD. This sensitivity to vOCs is not unique to
one LeD manufacturer but is a known problem for all types of
blue, royal blue and white-light LeDs. Chemical incompatibility
in SSL is often a localized phenomenon that occurs in luminaire
designs that seal portions of the system, resulting in an LeD
operating environment having elevated temperatures with little
or no air movement. However, with proper design and adequate
testing, chemical incompatibility effects can be prevented.
Cree maintains lists of chemicals known to be incompatible with
www.cree.com/Xlamp
XLamp LeDs and has partnered with materials manufacturers
to inform our customers with information on acceptable
materials. These lists are in the Appendix at the end of this
document. Customer testing is a good way to further develop
an understanding of chemical incompatibilities of a new LeD
Copyright © 2011-2018 Cree, Inc. All rights reserved. The information in this document is subject to change without notice. Cree
®
and XLamp
®
are
registered trademarks and the Cree logo is a trademark of Cree, Inc. Other trademarks, product, and company names are the property of their respective
owners and do not imply specific product and/or vendor endorsement, sponsorship or association. This document is provided for informational
purposes only and is not a warranty or a specification. For product specifications, please see the data sheets available at www.cree.com. For warranty
information, please contact Cree Sales at sales@cree.com.
Cree, Inc.
4600 Silicon Drive
Durham, NC 27703
USA Tel: +1.919.313.5300
XLamp
®
LED ChEmiCaL CompatibiLity
lighting design. With proper material selection design and testing, chemical incompatibility effects can be minimized or removed from
SSL designs.
baCkgrounD anD inTroDuCTion
Most SSL luminaire types are implemented with a blue light LeD chip covered with a yellow phosphor and silicone encapsulant to convert
the blue light to a broader white light spectrum. This entire LeD assembly is covered by a silicone-based lens. Figure 2 is a cross-section
drawing of a typical lighting-class LeD.
Silicone Lens
Blue LED Chip
Covered by Phosphors
& Silicone Encapsulant
Cathode
Tsp
Anode
Substrate
figure 2: Cross-sectional structure of a typical lighting-class LED
The unique silicone polymers utilized in LeDs have excellent light transmittance characteristics: stable over wide temperature ranges,
resistant to yellowing due to ultraviolet (uv) exposure and easily molded. This results in a high-performance yet cost-effective LeD. The
basic structure of the LeD’s lens and encapsulants is a silicone polymer, which is a stable chemical compound.
Any vOCs present in an SSL system can diffuse into the gas-permeable silicone lens and encapsulants of the LeD. Within the molecular
structure of these silicone materials, the vOCs will occupy a free space in the interwoven silicone polymer. With subsequent exposure
to high photon energy emitted from the LeD, along with the heat from the lighting system and the environment, the volatile compounds
trapped in the LeD‘s lens or encapsulants can discolor. This discoloration of the trapped vOCs can degrade the light emitted from the
LeD. This discoloration tends to occur in blue, royal blue and white-light producing LeDs that use blue wavelength LeD chips with yellow
phosphors for spectrum conversion. This sensitivity to vOCs is not unique to one LeD manufacturer but is a known problem for all types
of blue, royal blue and white-light LeDs. Chemically induced discoloration is less prevalent and not as noticeable with amber, red and
green LeDs; these color LeDs have longer wavelengths and therefore a lower frequency and produce lower photonic energy compared to
blue LEDs. Photonic energy (E) is defined by the Planck-Einstein equation of E = hf, where h is Planck’s constant and f is frequency, thus
a higher frequency produces a higher photonic energy.
This application note presents:
real-world examples of discoloration caused by vOCs
Sources of chemical incompatibility from the general classes of materials used in SSL systems
Discussion and examples of the reversibility of discoloration from vOCs
Cree’s recommended best practices to maintain chemical compatibility
Copyright © 2011-2018 Cree, Inc. All rights reserved. The information in this document is subject to change without notice. Cree
®
and XLamp
®
are registered trademarks and the Cree logo is a trademark
of Cree, Inc. Other trademarks, product, and company names are the property of their respective owners and do not imply specific product and/or vendor endorsement, sponsorship or association. This
document is provided for informational purposes only and is not a warranty or a specification. For product specifications, please see the data sheets available at www.cree.com. For warranty information,
please contact Cree Sales at sales@cree.com.
2
XLamp
®
LED ChEmiCaL CompatibiLity
Procedures and test processes for measuring and assessing potential chemical interactions
Chemical incompatibility test results
EXampLEs of ChEmiCaL inCompaTibiLiTy
This section contains multiple examples of real-life discoloration caused by vOCs. Figures 3 and 4 show a luminaire based on six XLamp
Xr-e LeDs. Figure 3 shows the light output at initial turn-on and Figure 4 shows the same luminaire after less than 100 hours of operation.
Figure 4 shows significant yellowing of the light output, which is likely caused by a color shift in the LEDs. It is worth noting the space
have caused this discoloration of the surface of the LeDs.
Your Customer Has Developed a Great
plate is a nearly sealed microenvironment. The most likely explanation is that vOCs
LED Fixture.
But wait …. What Has Happened?
between the circuit board and the external optical
figure 3: XLamp Xr-E LED-based luminaire at initial illumination
figure 4: XLamp Xr-E LED-based luminaire, yellowed after 100 hours
From left to right in Figure 5 is a pictorial representation of a silicone polymer as vOCs are introduced that occupy the free spaces in the
silicone. After exposure to heat and high photonic energy, this introduction results in vOC-based discoloration.
Copyright © 2009, Cree, Inc.
Cree Confidential
pg. 1
Copyright © 2009, Cree, Inc.
Cree Confidential
pg. 2
figure 5: Left to right - silicone chains; voCs occupying free spaces in the silicone;
discoloration as a result of voC exposure to heat and photonic energy
using chemicals containing vOCs in manufacturing SSL systems can result in LeD light quality degradation or even complete luminaire
failure. Figure 6 illustrates the degradation effect from a vOC on the silicone encapsulant that covers the LeD chip.
Cree Confidential
Copyright © 2011-2018 Cree, Inc. All rights reserved. The information in this document is subject to change without notice. Cree
®
and XLamp
®
are registered trademarks and the Cree logo is a trademark
of Cree, Inc. Other trademarks, product, and company names are the property of their respective owners and do not imply specific product and/or vendor endorsement, sponsorship or association. This
document is provided for informational purposes only and is not a warranty or a specification. For product specifications, please see the data sheets available at www.cree.com. For warranty information,
please contact Cree Sales at sales@cree.com.
3
Appearance of Normal and Discolored LEDs
XLamp
®
LED ChEmiCaL CompatibiLity
figure 6: Examples of normal (left) and voC degraded LED (right)
The photograph on the left in Figure 6 is the normal appearance of a Cree XLamp LeD. On the right, the same type of XLamp LeD chip has
a pronounced brown discoloration due to exposure to vOCs while in operation with high photonic power output at nominal environmental
temperatures. This discoloration of the encapsulants is on the top of the LeD chip, localized to the area just above the chip surface,
closest to the source of heat and high photon energy. note that discoloration can occur at various points in an LeD’s lifetime; factors that
affect discoloration of vOCs include heat, photonic energy and wavelength. Figure 7 shows several examples of the effects of chemical
incompatibility in the LeDs.
Cree Confidential
Examples of chemical incompatibility with XP
figure 7: a variety of XLamp LEDs showing chemical incompatibility
vOC-based discoloration can occur as a result of outgassing of solid materials. The sequence of pictures in Figure 8 documents just such
a case of chemical incompatibility. Cree investigated the source of LeD discoloration and, even though the LeDs were not in a sealed
environment, an LeD on the luminaire discolored, as shown in the upper left photograph.
Cree Confidential
12
Copyright © 2011-2018 Cree, Inc. All rights reserved. The information in this document is subject to change without notice. Cree
®
and XLamp
®
are registered trademarks and the Cree logo is a trademark
of Cree, Inc. Other trademarks, product, and company names are the property of their respective owners and do not imply specific product and/or vendor endorsement, sponsorship or association. This
document is provided for informational purposes only and is not a warranty or a specification. For product specifications, please see the data sheets available at www.cree.com. For warranty information,
please contact Cree Sales at sales@cree.com.
4
XLamp
®
LED ChEmiCaL CompatibiLity
Materials Used in SSL Luminaires Can Have a Negative Impact
Materials Used in SSL Luminaires Can Have a Negative Impact
figure 8: sequence of voC investigation
Cree Confidential
The root cause of the problem was revealed as the disassembled unit sat overnight on a white piece of paper. The next day, indication of
outgassing from the small gaskets was evident on the paper, as shown in Figure 9. The gasket material, in close contact with the LeD lens,
offered a source of vOCs, which ultimately led to the LeD’s discoloration. This case demonstrates the importance of testing all chemicals
and materials in the specific application and environment for which they are intended to be used.
Cree Confidential
figure 9: Evidence of voC outgassing from an o-ring
Cree Confidential
Copyright © 2011-2018 Cree, Inc. All rights reserved. The information in this document is subject to change without notice. Cree
®
and XLamp
®
are registered trademarks and the Cree logo is a trademark
of Cree, Inc. Other trademarks, product, and company names are the property of their respective owners and do not imply specific product and/or vendor endorsement, sponsorship or association. This
document is provided for informational purposes only and is not a warranty or a specification. For product specifications, please see the data sheets available at www.cree.com. For warranty information,
please contact Cree Sales at sales@cree.com.
5
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参数对比
与CCK-18LED相近的元器件有:CCK-6XRE、CCK-6XPE。描述及对比如下:
型号 CCK-18LED CCK-6XRE CCK-6XPE
描述 LED Lighting Development Tools Deluxe Chemical Compatibility Kit LED Lighting Development Tools XR-E Chemical Compatibility Kit LED Lighting Development Tools XP-E Chemical Compatibility Kit
Product Attribute Attribute Value Attribute Value Attribute Value
制造商
Manufacturer
Cree(科瑞) Cree(科瑞) Cree(科瑞)
产品种类
Product Category
LED Lighting Development Tools LED Lighting Development Tools LED Lighting Development Tools
RoHS Details Details Details
产品
Product
Test Kits Test Kits Test Kits
用于
For Use With
18 LEDs XR-E XP-E
Description/Function Chemical compatability kit Chemical compatability kit Chemical compatability kit
工厂包装数量
Factory Pack Quantity
10 10 10
Core - XR-E XP-E
工作电源电压
Operating Supply Voltage
- 18 V 18 V
Output Current - 700 mA 700 mA
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